Synthesis of and excited state processes in multichromophoric dendritic systems |
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Authors: | Andrew C. Grimsdale,Marc Lor,Satoshi Habuchi,Frans C. De Schryver,Klaus Mü llen |
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Affiliation: | a Max-Planck-Institut für Polymerforschung, Ackermannweg 10, D-55128 Mainz, Germany b Department of Chemistry, Katholieke Universiteit Leuven, Celestijnenlaan 200 F, B-3001 Heverlee, Belgium |
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Abstract: | Rigid polyphenylene dendrimers substituted with dyes are suitable substrates for the investigation of interchromophore photophysical processes as they contain discrete numbers of chromophores in well-defined spatial relationships to each other. In this contribution, we provide an overview of the synthesis of such materials and show how a combination of ensemble and single-molecule spectroscopic investigations can be used to elucidate the interchromophore excitation energy transfer processes in them. |
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Keywords: | 31.50.Df 34.30.+h 33.50.Dq 06.60.Jn |
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