| Synthesis and Characterization of Chiral Binuclear Organolanthanide and Yttrium Alkoxides Containing Cyclopentadienyl Ligand |
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| 引用本文： | Chang Tao QIAN, Tai Sheng HUANG (Laboratory of Organometallic Chemistry,Shanghai Institute of Organic Chemistry,ChineseAcademy of Sciences,354 Fenglin Lu,Shanghai 200032). Synthesis and Characterization of Chiral Binuclear Organolanthanide and Yttrium Alkoxides Containing Cyclopentadienyl Ligand[J]. 中国化学快报, 1998, 0(8) |
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| 作者姓名： | Chang Tao QIAN Tai Sheng HUANG (Laboratory of Organometallic Chemistry Shanghai Institute of Organic Chemistry ChineseAcademy of Sciences 354 Fenglin Lu Shanghai 200032) |
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| 作者单位： | Laboratory of Organometallic Chemistry，Shanghai Institute of Organic Chemistry，ChineseAcademy of Sciences，354 Fenglin Lu，Shanghai 200032 |
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| 摘 要： | Recently,variousdimericlanthanidealkoxidesofthetype[(Ln(p-oR)(Cp)2}2]havebeenpreparedbytreatmentofthechlorocomplexeswithsodiumalkoxideslorprotonationofLn(Cp)3withstoichiometricamountsofalcohols2.Butthechiralorganolanthanidepolymericalkoxidescontainingcyclopentadienylgroupsandopticallypurediolligandshavenotbeenreporteduptonow3.Furthermore,themethodofprotonationisusuallyappliedinnon-coordinatingsolventssuchasheptane,hexane,benzeneandtoluene.Inthispaper,wewishtoreportthefirstsynthesisofchiralcy…
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Synthesis and Characterization of Chiral Binuclear Organolanthanide and Yttrium Alkoxides Containing Cyclopentudienyl Ligand |
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| Chang Tao QIAN, Tai Sheng HUANG. Synthesis and Characterization of Chiral Binuclear Organolanthanide and Yttrium Alkoxides Containing Cyclopentudienyl Ligand[J]. Chinese Chemical Letters, 1998, 0(8) |
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| Authors: | Chang Tao QIAN Tai Sheng HUANG |
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| Abstract: | |
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| Keywords: | chiral organolanthanide alkoxides cyclopentadienyl |
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