| 三分子反应在—维介质上的动力学行为 |
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| 引用本文： | 万荣,胡宏,李如生.三分子反应在—维介质上的动力学行为[J].高等学校化学学报,1996(10). |
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| 作者姓名： | 万荣 胡宏 李如生 |
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| 作者单位： | 清华大学化学系 |
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| 摘 要： | 提出了一种简明的理论分析方法，求出了三分子反应Ａ＋２Ｘ ３Ｘ在一维介质上的动力学行为的解析解，并成功地解决了该反应动力学行为对初始条件的依赖性问题。还通过数值模拟证实了提出的理论方法的正确性。
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| 关 键 词： | 一维介质，三分子反应，化学动力学 |
Dynamic Behavior of Trimolecular Reaction in One Dimension Medium |
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| WAN Rong,HU Hong,LI Ru-Sheng.Dynamic Behavior of Trimolecular Reaction in One Dimension Medium[J].Chemical Research In Chinese Universities,1996(10). |
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| Authors: | WAN Rong HU Hong LI Ru-Sheng |
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| Abstract: | It is well known that the dynamic behavior of chemical reactions in fractional or low dimension medium is greatly different from that ruled by the classical chemical dynamics.In this paper,the anomalous dynamic behavior of trimolecular reaction A+2X3X in one dimension medium is studied.A new theoretical method is developed,by which an analytical solution to the dynamic behavior of this reaction under different initial conditions is obtained.In addition,this new method is verified by the results based on some numerical simulations. |
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| Keywords: | One dimension medium Trimolecular reaction Chemical kinetics |
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