Cyanide (13)C NMR hyperfine shifts in paramagnetic cyanide-bridged mixed-valence complexes |
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| Authors: | Laidlaw W Michael Denning Robert G |
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| Institution: | Inorganic Chemistry Laboratory, South Parks Road, Oxford, UK OX1 3QR. michael.laidlaw@chem.ox.ac.uk |
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| Abstract: | Paramagnetic (hyperfine) NMR shifts in the (13)C cyanide bridge and (31)P resonances in a set of mixed valence complexes (eta(5)-C(5)R(5))Ru(PPh(3))L((13)CN)Ru(NH(3))(5)](n+) (R = H; L = PPh(3), CO, NO(+); R = Me; L = PPh(3)) are sensitive to the extent of intermetallic charge-transfer, and are strongly solvent dependent. |
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