Effect of competing binding modes on retention in chromatography and capillary electrophoresis. A theoretical consideration |
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| Authors: | Leonid D. Asnin Yuliya Nikitina |
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| Affiliation: | Perm National Research Polytechnic University, Department of Chemistry and Biotechnology, Perm, Russian Federation |
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| Abstract: | A mathematical formalism has been developed to describe equilibrium in a system involving a single selector and a selectand molecule capable of binding to this selector by different modes. The generalization of this model to a multiselector system has also been considered. Applications of the developed equations in chromatography and CE are discussed. |
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| Keywords: | Binding Capillary electrophoresis Chromatography Equilibrium |
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