Determination of the Rate Constant of the Reaction of CCl2 with HCl

The rate constant of the reaction between CCl₂ radicals and HCl was experimentally determined. The CCl₂ radicals were obtained by infrared multiphoton dissociation of CDCl₃. The time dependence of the CCl₂ radicals' concentration in the presence of HCl was determined by laser‐induced fluorescence. The experimental conditions allowed us to associate the decrease in the concentration of radicals to the self‐recombination reaction to form C₂Cl₄ and to the reaction with HCl to form CHCl₃. The rate constant for the self‐recombination reaction was determined to be in the high‐pressure regime. The value obtained at 300 K was (5.7 ± 0.1) × 10^?13 cm³ molecule^?1 s^?1, whereas the value of the rate constant measured for the reaction with HCl was (2.7 ± 0.1) × 10^?14 cm³ molecule^?1 s^?1.