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Fitting formula for the injection volume of a gas chromatograph for radio‐xenon sampling in the lower troposphere
Authors:Liu Shu‐jiang  Chen Zhan‐ying  Wang Shi‐lian  Chang Yin‐zhong  Li Qi  Fan Yuan‐qing  Zhao Yun‐gang  Jia Huai‐mao  Zhang Xin‐jun  Wang Jun
Institution:CTBT Beijing National Data Centre and Radionuclide Laboratory, Beijing, China
Abstract:GC is usually used for xenon concentration and radon removal in the International Monitoring System of the Comprehensive Nuclear‐Test‐Ban Treaty. In a gas chromatograph, the injection volume is defined to calculate the column capacity. In this paper, the injection volume was investigated and a fitting formula for the injection volume was derived and discussed subsequently. As a consequence, the xenon injection volume exponentially decreased with the column temperature increased, but exponentially increased as the flow rate increased.
Keywords:Atmospheric chemistry  gas chromatography  Injection volume  Radio‐xenon sampling
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