The Intermetallic Type-I Clathrate Na8Zn4Ge42 |
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Authors: | Saskia Stegmaier Viktor Hlukhyy Thomas F Fässler |
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Institution: | Department of Chemistry, Technische Universität München, Lichtenbergstraße 4, 85747 Garching, Germany |
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Abstract: | The new intermetallic type-I clathrate Na8Zn4Ge42 was obtained by direct reaction of the elements, and its crystal structure was determined by means of single-crystal X-ray diffraction methods. The structure is described in space group Pm3 n (no. 223) with a = 10.6982(1) Å. A mixed Zn/Ge occupancy is found for one of the network sites (6c). Na8Zn4Ge42 represents an air-stable electron-precise Zintl phase with exclusively Na cations located in the cavities of a polyanionic host network of four-connected Zn and Ge atoms. |
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Keywords: | Type-I clathrate Germanium Zinc Crystal structure Zintl phase |
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