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Tribological behaviors of DLC films in sulfuric acid and sodium hydroxide solutions
Authors:Wensheng Li  Dongqing He  Wei Ren  Liping Wang  Lunling Shang  Guangan Zhang
Affiliation:1. State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals, Lanzhou University of Technology, Lanzhou, China

School of Materials Science and Engineering, Lanzhou University of Technology, Lanzhou, China;2. State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals, Lanzhou University of Technology, Lanzhou, China;3. School of Materials Science and Engineering, Lanzhou University of Technology, Lanzhou, China;4. School of Materials Science and Engineering, Lanzhou University of Technology, Lanzhou, China

State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, China;5. State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, China

Abstract:Tribological behaviors of three typical kinds of diamond-like carbon (DLC) films (a-C, a-C:Cr, and a-C:H) in sulfuric acid and sodium hydroxide solutions were investigated. The a-C film showed the lowest stable coefficients of friction (COF) in both sulfuric acid and sodium hydroxide solutions but the worst wear resistance in sulfuric acid solution. The a-C:H film showed the highest COF in sulfuric acid solution and the best wear resistance in both sulfuric acid and sodium hydroxide solutions. The a-C:Cr film exhibited superior comprehensive tribological performance in sulfuric acid solution, while in sodium hydroxide solution, high COF and very poor wear resistance was observed. What is more, friction and wear mechanism was revealed by investigating the friction-induced material evolutions on the sliding surface.
Keywords:corrosion-wear  corrosive solutions  DLC films  tribological behaviors
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