Keto-stabilized Arsenic Ylides and their Coordination to Gold(I) |
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| Authors: | Ferdinand Ehlers Jana M Strumberger Fabian Mohr |
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| Institution: | Anorganische Chemie, Fakultät für Mathematik und Naturwissenschaften, Bergische Universität Wuppertal, Gaußstr. 20, 42119 Wuppertal, Germany |
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| Abstract: | Three different arsonium salts were prepared by a solvent-free method from Ph3As and the respective 2-bromoacetophenones. These salts were deprotonated by NaOH to form keto-stabilized arsenic ylides. The ylids react with AuCl(tht)] affording gold(I) complexes containing the C-bound ylide. The compounds were characterized by NMR spectroscopy, IR spectroscopy, and X-ray diffraction. |
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| Keywords: | Arsonium salts Gold Ylide |
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