Fluorine in Small Molecules: Fluoromethyl Azide and Chalcogenocyanates |
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| Authors: | Marco Reichel Mara Egenhöfer Burkhard Krumm Konstantin Karaghiosoff |
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| Institution: | Department of Chemistry, Ludwig-Maximilian University of Munich, Butenandtstr. 5–13(D), 81377 Munich, Germany |
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| Abstract: | Fluoromethylating agents are a highly studied and controversely discussed class of compounds. New fluoromethyl pseudohalides FCH2N3, FCH2SCN, and FCH2SeCN were prepared for the first time and their physical and spectroscopic properties investigated. Their synthesis is performed conveniently by fluoromethylation of the respective silver or potassium pseudohalogenides with fluoroiodomethane. |
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| Keywords: | Fluoromethyl pseudohalides Fluoroiodomethane Fluoromethylation Isotope effects NMR spectroscopy |
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