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Evolution of Cu(In,Ga)Se2 surfaces under water immersion monitored by X-ray photoelectron spectroscopy
Authors:Solène Béchu  Muriel Bouttemy  Jackie Vigneron  Daniel Lincot  Jean-François Guillemoles  Arnaud Etcheberry
Institution:1. Institut Lavoisier de Versailles (ILV), Université Paris-Saclay, CNRS-UVSQ, Versailles, France;2. CNRS-IPVF, Palaiseau, France
Abstract:Cu(In,Ga)Se2 absorbers were immerged in deionized water for different times, and specific chemical evolutions were monitored thanks to X-ray photoemission spectroscopy. Cu(In,Ga)Se2 related dissolution products were studied in water through induced coupled plasma optical emission spectroscopy. From those analyses, specific surface network disorganization was observed, with Cu migration towards the surface, leading to different kinetics of oxidation and dissolution for each element that could be quantified.
Keywords:Cu(In  Ga)Se2  water aging  XPS
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