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Redox polymers incorporating pendant 6-oxoverdazyl and nitronyl nitroxide radicals |
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| Authors: | Michael Anghel François Magnan Sara D. Catingan Matthew A. McCready Elaheh Aawani Victor Wong Deepa Singh Giovanni Fanchini Joe B. Gilroy |
| Affiliation: | 1. Department of Chemistry, The University of Western Ontario, London, Ontario, N6A 5B7 Canada The Centre for Advanced Materials and Biomaterials Research (CAMBR), The University of Western Ontario, London, Ontario, N6A 5B7 Canada Department of Physics and Astronomy, The University of Western Ontario, London, Ontario, N6A 3K7 Canada;2. The Centre for Advanced Materials and Biomaterials Research (CAMBR), The University of Western Ontario, London, Ontario, N6A 5B7 Canada Department of Physics and Astronomy, The University of Western Ontario, London, Ontario, N6A 3K7 Canada;3. Department of Chemistry, The University of Western Ontario, London, Ontario, N6A 5B7 Canada |
| Abstract: | Polymers comprised of redox-active organic radicals have emerged as promising materials for use in a variety of organic electronics, including fast-charging batteries. Despite these advances, relatively little attention has been focused on the diversification of the families of radicals that are commonly incorporated into polymer frameworks, with most radical polymers being comprised of nitroxide radicals. Here, we report two new examples prepared via ring-opening methathesis polymerization containing 6-oxoverdazyl and nitronyl nitroxide radicals appended to their backbones. The polymerization reaction and optoelectronic properties were explored in detail, revealing high radical content and redox activity that may be advantageous for their use as semiconducting thin films. Initial studies revealed that current–voltage curves obtained from thin films of the title polymers exhibited memory effects making them excellent candidates for use in resistive memory applications. © 2020 Wiley Periodicals, Inc. J. Polym. Sci. 2020 , 58, 309–319 |
| Keywords: | 6-oxoverdazyl nitronyl nitroxide polymer thin films redox polymers ring-opening metathesis polymerization stable radical polymers |