Abstract: | Ring inversion of eight substituted 2-phenyl-4, 4-dimethyloxazolidines in o-dichlorobenzene-d4 was studied by 1H DNMR. Very high inversion barriers (ΔGo≠ = 86.7–93.4 kJ·mol?1) were found for these oxazolidine rings. The magnitude of the inversion barrier is dependent on the polarity of the substituent on the phenyl group. A linear correlation is present between the ΔGo≠ of the inversion and the substituent constant, σ+, of the substituent. |