Studies on the alcohol exchange reactions of methoxide ditungsten [W(IV)] compound W2Cl4(OCH3)4 (CH3OH)2, prepared from (n-Bu4N)3W2Cl9 |
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| Authors: | Bo Hong Song-Lin Jin Ku Yih-Tong Ming-Qin Chen |
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| Affiliation: | Bo Hong,Song-Lin Jin,Ku Yih-Tong (Gu,Yi-Dong),Ming-Qin Chen |
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| Abstract: | (n-Bu4N)3W2Cl9, prepared from K3W2Cl9, can be readily converted to a series of [W(IV)] cluster compounds, W2Cl4 (μ-OR)2 (OR')2 (R'OH)2, including seven known compounds and two new compounds with R=Me, R'=i-Pr and sec-Bu. The crystallographic data of 7 and 8 are hereby presented. |
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