Highly enantioselective aerobic oxidation of alpha-hydroxyphosphonates catalyzed by chiral vanadyl(V) methoxides bearing N-salicylidene-alpha-aminocarboxylates |
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| Authors: | Pawar Vijay D Bettigeri Sampada Weng Shiue-Shien Kao Jun-Qi Chen Chien-Tien |
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| Institution: | Department of Chemistry, National Taiwan Normal University, Taipei, Taiwan. |
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| Abstract: | An unprecedented vanadyl(V) methoxide complex 4 derived from 3,5-dibromo-N-salicylidene-l-tert-leucinate enables highly enantioselective aerobic oxidations of alpha-hydroxyphosphonates at ambient temperature with selectivity factors ranging from 3 to >99. |
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