Redox Potentials of Samarium and Europium in Molten Cesium Chloride |
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| Authors: | Novoselova A V Khokhlov V A Shishkin V Yu |
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| Institution: | (1) Institute of High-Temperature Electrochemistry, Ural Division, Russian Academy of Sciencesd, Yekatirenburg, Russia |
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| Abstract: | The method of direct potentiometry was applied to measure redox potentials of Sm3
+/Sm2
+ and Eu3
+/Eu2
+ in molten cesium chloride relative to chlorine reference electrode in the temperature range 973-1173 K. Changes in the Gibbs energy of the redox reaction LnCl2(l) + 1/2Cl2(g)  LnCl3(l) were calculated. |
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| Keywords: | |
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