It all began with an error: the nomofungin/communesin story |
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Authors: | Siengalewicz Peter Gaich Tanja Mulzer Johann |
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Institution: | Department of Organic Chemistry, University of Vienna, Waehringerstrasse 38, 1090 Vienna, Austria. |
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Abstract: | The communesin/nomofungin/perophoramidine story is an impressive example of how biogenetic considerations can lead to the correction of structural misassignments and inspire synthetic chemists with new, fruitful ideas. Intensive studies by a number of research groups culminated in the total synthesis of perophoramidine by the Funk research group in 2004. In 2007, Qin and co-workers completed the first total synthesis of a communesin. |
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Keywords: | alkaloids biosynthesis nomofungin perophoramidine total synthesis |
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