| Synthesis and Structure of 4—Nitrobenzaldehyde Thiosemicarbazone |
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| 引用本文： | 田玉鹏,罗保生,等.Synthesis and Structure of 4—Nitrobenzaldehyde Thiosemicarbazone[J].结构化学,1996,15(4):307-310. |
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| 作者姓名： | 田玉鹏 罗保生 等 |
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| 作者单位： | Coordination Chemistry Institute，State Key Laboratory of Coordinatton Chemistry，Nanjing Univuersity，Centre for Advanced Studies in Science and Technology of Microstructure，Hanjing，210093 |
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| 摘 要： | ＳｙｎｔｈｅｓｉｓａｎｄＳｔｒｕｃｔｕｒｅｏｆ４－ＮｉｔｒｏｂｅｎｚａｌｄｅｈｙｄｅＴｈｉｏｓｅｍｉｃａｒｂａｚｏｎｅＴｉａｎＹｕ－Ｐｅｎｇ；ＤｕａｎＣｈｕｎ－Ｙｉｎｇ；ＬｕＺｈｏｎｇ－Ｌｉｎ；ＹｏｕＸｉａｏ－Ｚｅｎｇ（ＣｏｏｒｄｉｎａｔｉｏｎＣｈｅ...
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| 关 键 词： | 合成 分子结构 4－硝基苯甲醛缩氨基硫脲 |
Synthesis and Structure of 4-Nitrobenzaldehyde Thiosemicarbazone |
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| Tian Yu-Peng ,Duan Chun-Ying, Lu Zhong-Lin, You Xiao-Zeng.Synthesis and Structure of 4-Nitrobenzaldehyde Thiosemicarbazone[J].Chinese Journal of Structural Chemistry,1996,15(4):307-310. |
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| Authors: | Tian Yu-Peng Duan Chun-Ying Lu Zhong-Lin You Xiao-Zeng |
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| Institution: | [1]CoordinationChemistryInstitute,StateKeyLaboratoryo [2]CoordinationChemistryInstitut,StateKeyLaboratoryo |
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| Abstract: | Nitrobenzaldehyde thiosemicarbazone (C_8H_8N_4O_2S) has been prepared by the condensation of 4-nitrobenzaldehyde with thiosemicarbazide. This compound crystallized in monoclinic space group P2_1/c with the unit cell parameters : a =4. 560(2), b=24. 900(4), c=8. 950(2) A, β=98. 37(2)°, V=1005. 2 A￣3, Z=4,D_c = 1. 482 g/cm￣3, λ= 0. 71073 A, μ(MoKα)=0. 293 mm￣(-1) , final R= 0.044 for 1568 observed reflections. Analvsis of molecular structure reveals that the molecule is in trans-configuration. The molecular packing is governed by N-H...S and O... H-N hydrogen bonding interactions. |
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| Keywords: | molecular structure thiosemicarbazone 4-nitrobenzaldehyde thiosemicarhazone |
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