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Photochemical Reactions in Gaseous Mixtures of C2F4 and CF3I
Authors:Fokanov  V P  Pavlov  A B  Semenov  V N  Morozov  A V
Institution:(1) Prikladnaya Khimiya Russian Scientific Center, St. Petersburg, Russia
Abstract:Products of photochemical reactions occurring in gaseous mixtures of C2F4 and CF3I under vacuum-UV irradiation were studied. The major photolysis products are linear perfluoroparaffins C n F2n+2 and linear perfluoroalkyl iodides C n F2n+2I. The product ratio is consistent with the suggested kinetic scheme of chain reactions of telomers.
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