Photochemical Reactions in Gaseous Mixtures of C2F4 and CF3I |
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Authors: | Fokanov V P Pavlov A B Semenov V N Morozov A V |
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Institution: | (1) Prikladnaya Khimiya Russian Scientific Center, St. Petersburg, Russia |
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Abstract: | Products of photochemical reactions occurring in gaseous mixtures of C2F4 and CF3I under vacuum-UV irradiation were studied. The major photolysis products are linear perfluoroparaffins C
n
F2n+2 and linear perfluoroalkyl iodides C
n
F2n+2I. The product ratio is consistent with the suggested kinetic scheme of chain reactions of telomers. |
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