Fabrication of a molecular-level multilayer film on organic polymer surfaces via chemical bonding assembly |
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Authors: | Zhao Hongchi Yang Peng Deng Jianping Liu Lianying Zhu Jianwu Sui Yuan Lu Jiaoming Yang Wantai |
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Institution: | State Key Laboratory of Chemical Resource Engineering and College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, People's Republic of China. |
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Abstract: | A fresh multilayer film was fabricated on a molecular level and successfully tethered to the surface of a hydroxylated organic substrate via chemical bonding assembly (CBA). Sulfate anion groups (SO4-) were preintroduced onto the surface of biaxially oriented polypropylene (BOPP) films via a reference method. Upon hydrolysis of the SO4- groups, hydroxyl groups (--OH) were formed that subsequently acted as initial reagents for a series of alternate reactions with terephthalyl chloride (TPC) and bisphenol A (BPA). A stable and well-defined multilayer film was thus fabricated via the CBA method. As a result of the nanoscale multilayer fresh film being abundant with reactive groups, it is believed that the film and its fabrication method should provide a fundamental platform for further surface functionalization and direct the design of advanced materials with desired properties. |
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