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The evolution of the cluster size distribution in a coagulation system
Authors:Binglin Lu
Affiliation:(1) Department of Chemistry, University of Copenhagen, DK-2100 Copenhagen, Denmark;(2) Present address: Fushun Petroleum Institute, Liaoning, China
Abstract:The coagulation equation with kernelKij=A+B(i+j)+Cij and arbitrary initial conditions is studied analytically and a simple expression for the solution is found. For monodisperse initial conditions, we recover the known size distribution expressed in terms of a degeneracy factorNk, which is determined by a recursion relation. For polydisperse initial conditions, a similar solution form is found, which includes a degeneracy factorNkl, also determined by a recursion relation. The physical meaning ofNkl and the recursion relation is given. A method to get explicit expressions forNk andNkl is illustrated. Finally, the pre-gel solution is given explicitly and a general method to get the post-gel solution is proposed.
Keywords:Smoluchovski equation  polycondensation  Flory-Stockmayer theory, degeneracy factor  gelation  post-gel solution
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