High-nuclearity silver ethynide clusters assembled with phosphonate and metavanadate precursors |
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| Authors: | Yun-Peng Xie Thomas C W Mak |
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| Affiliation: | Department of Chemistry and Center of Novel Functional Molecules, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong SAR (P.R. China). |
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| Abstract: | Giant mixed-metal clusters have been assembled with the multinuclear silver(I) tert-butylethynide supramolecular synthon and phosphonate-functionalized oxovanadate building blocks as surface components. Various anionic species can be used as their encapsulated templates. (Picture: Ag(36) cluster anion encapsulating a chloride (sphere) and two [(O(2) )(V(2) O(6) )](4-) template anions (dark green); Ag?blue, O?red, P?yellow, V?green). |
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| Keywords: | clusters ethynide oxovanadates phosphonates silver |
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