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Rhodium(III)- and Ruthenium(II)-Catalyzed Olefination of Isoquinolones |
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| Authors: | Peng Zhao Rui Niu Fen Wang Keli Han Xingwei Li |
| Affiliation: | Dalian Institute of Chemical Physics, Chinese Academy of Sciences , Dalian 116023, P. R. China. |
| Abstract: | NH and N-protected isoquinolones undergo Rh(III)-catalyzed oxidative olefination at the 8-position. Complementary redox-neutral olefination of such isoquinolones using internal alkynes was achieved under ruthenium catalysis. |
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