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An alternative synthesis of a sex pheromone of the dry bean beetleCallosobruchus analis |
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| Authors: | N. Ya. Grigor'eva P. G. Tsiklauri O. A. Pinsker |
| Affiliation: | (1) N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913 Moscow, Russian Federation |
| Abstract: | A formal total synthesis of 3-methylhept-2(Z)-enoic acid, a sex pheromone of the dry bean beetleCallosobruchus analis, was performed on the basis of a highly stereoselective version of the Peterson olefination of ketones developed previously by the authors. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1389–1392, July, 1999. |
| Keywords: | stereoselective version of the Peterson olefination of ketones insect pheromones 3-methylhept-2(Z)-enoic acid 3-phenylthiohexan-2-one methyl andtert-butyl 3-methyl-4-phenylthiohept-2(Z)- and-2(E)-enoate 3-methyl-4-phenylthiohept-2(Z)- and-2(E)-enols |
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