EMK-Messungen in binären ladungsunsymmetrischen Salzschmelzen aus Bariumchlorid und Alkalimetallchloriden |
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| Authors: | H-H Emons G Brutigam R Scheunpelug |
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| Institution: | H.-H. Emons,G. Bräutigam,R. Scheunpelug |
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| Abstract: | EMF Measurements in Binary Chargeunsymmetrical Salt Melts of Barium- and Alkali Chlorides The EMF is measured of cells with transference of the type Cl2C]/MCl//MCl? BaCl2(x)/C]Cl2 in the molten mixtures BaCl2? MCl (M ? Li, Na, K, Rb, Cs). From the EMF values and values of activities from another independent methods the transference numbers of the cations Ba2+ and M+ relative to the chloride ion in the molten mixtures BaCl2? (Li, Na, K) Cl are calculated. The values of activities for the system BaCl2? LiCl are calculated from cryoscopic analysis of the phase diagram. |
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