Institution: | aDepartment of Chemistry, Marmara University, Göztepe 34722, Istanbul, Turkey bDepartment of Physics, Marmara University, Göztepe 34722, Istanbul, Turkey cDepartment of Chemistry, University of Hacettepe, 06532 Ankara, Turkey dDepartment of Chemistry, Technical University of Istanbul, 34469 Maslak, Istanbul, Turkey |
Abstract: | Compounds 3 and 4 have been prepared by the reaction of 4-nitrocatechol 1 and 4-nitrophthalonitrile 2 by a common method, aromatic nucleophilic subtitution of the nitro group in 4-nitrophthalonitrile. Starting from 4 and 1-bromooctane, their alkylation reaction gave compound 5. Zn(II) 8, Co(II) 9 and Lu(III) 10 complexes were synthesized from the corresponding metal salts by the tetramerization of compound 5. Compound 7 was prepared by the statistical condensation of 5 and 4,5-bis(hexylthio)phthalonitrile 6 with CoCl2 · 6H2O in dry dimethylformamide. The new compounds were characterized by FT-IR, UV/Vis, NMR and mass spectra. The electrochemical properties of the complexes were also investigated by cyclic voltammetry in non-aqueous medium. The effect of temperature on the dc conductivity and the impedance spectra of spin coated film of the compounds was investigated at temperatures between 295 and 433 K and in the frequency range 40–105 Hz. Thermally activated conductivity dependence on temperature was observed for all compounds. |