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Practical dihydroxylation and C–C cleavage of unsaturated fatty acids |
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| Authors: | Michael A Oakley Simon Woodward Keith Coupland David Parker Clare Temple-Heald |
| Institution: | a Department of Chemistry, University of Hull, Kingston-upon-Hull HU6 7RX, UK b Croda Universal, Oak Road, Clough Road, Kingston-upon-Hull HU6 7PH, UK |
| Abstract: | Unsaturated fatty acids C8H17CH=CH(CH2)nCO2H] (n=7, 11) acids are cleanly dihydroxylated by hydrogen peroxide in the presence of catalytic amounts of H2WO4. Under molecular oxygen, in the presence of catalytic amounts of N-hydroxyphthalimide and Co(acac)3, the diols resulting from erucic (n=11) and oleic (n=7) acid undergo C–C cleavage. |
| Keywords: | Dihydroxylation C–C cleavage Unsaturated fatty acids |
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