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Electric polarization memory effect in a magnetoelectric multiferroic CuFe1−xGaxO2
Authors:Setsuo Mitsuda  Taro Nakajima  Motoyoshi Yamano  Keiichirou Takahashi  Hiroe Yamazaki  Kazuya Masuda  Yoshiaki Kaneko  Noriki Terada  Karel Prokes  Klaus Kiefer
Institution:aDepartment of Physics, Faculty of Science, Tokyo University of Science, Tokyo 162-8601, Japan;bICYS, National Institute for Materials Science, Tsukuba, Ibaraki 305-0044, Japan;cHelmholtz Centre Berlin for Materials and Energy, SF-2, Glienicker Str. 100, 14109 Berlin, Germany
Abstract:Magnetic oxide CuFeO2 is a magnetoelectric multiferroic with new type of spin–polarization coupling different from that in the spin-current mechanism, where magnetic field-induced or nonmagnetic impurity-induced proper helical magnetic ordering generates a spontaneous electric polarization parallel to the helical axis. Using a CuFe1−xGaxO2 sample with x=0.035, in which the single ferroelectric phase is realized below TNnot, vert, similar8 K in zero magnetic field unlike CuFe1−xAlxO2, we have performed pyroelectric current, thermally stimulated current (TSC) and polarized neutron diffraction measurements to study a memory effect that the electric polarization is partially preserved even for 2nd-cooling from above TN without poling electric field. It was found that the charge trapped during 1st-cooling with poling electric field, which is released as TSC on heating, plays an important role in the memory effect.
Keywords:Magnetoelectric multiferroic  CuFeO2  Spin frustration  Polarized neutron  Electric polarization  Memory effect
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