Synthesis of new chelating ligands containing two pyrazole fragments |
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Authors: | Kravtsov I V Baranin S V Dorokhov V A Zelinsky N D |
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Institution: | (1) Department of Chemistry, Seoul National University, Seoul, 151-747, Korea; |
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Abstract: | 7-Pyrazol-3(5)-yl]4,5,6,7-tetrahydro-1H-indazole and 6-pyrazol-3(5)-yl]-1,4,5,6-tetrahydrocyclopentac]pyrazole, potential chelating ligands, were synthesized by
condensation of 2-acetylcyclohexanone and 2-acetylcyclopentanone difluoroboron complexes with dimethylformamide dimethyl acetal
followed by cyclization with hydrazine hydrate. |
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