| 含桥式硫原子双酚盐配体的有机铋配合物的合成及其对CO2和环氧丙烷环加成反应催化性能的研究 |
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| 引用本文： | 尹双凤,代威力,李文生,周小平,岛田茂. 含桥式硫原子双酚盐配体的有机铋配合物的合成及其对CO2和环氧丙烷环加成反应催化性能的研究[J]. 分子催化, 2007, 21(3): 264-267 |
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| 作者姓名： | 尹双凤 代威力 李文生 周小平 岛田茂 |
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| 作者单位： | 1. 湖南大学,化学化工学院,湖南,长沙,410082
2. 日本国立综合产业技术研究所,日本茨城,305-8565 |
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| 基金项目： | Supported by the National Science Foundation of China(No.20507005) |
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| 摘 要： | 合成分析了含有桥式硫原子二酚盐配体的新型有机铋配合物,并发现它们在亲核试剂(I-)存在下对CO2和环氧丙烷环加成反应合成碳酸丙烯酯表现出很高的催化活性和选择性.
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| 关 键 词： | 有机配合物 二氧化碳 环氧丙烷 碳酸丙烯酯 环加成反应 |
| 文章编号： | 1001-3555（2007）03-0264-04 |
| 收稿时间： | 2006-08-23 |
| 修稿时间： | 2006-08-232006-12-14 |
Synthesis of Novel Organobismuth Complexes Bearing a Sulfur-bridged Biphenolate Ligand and Their Catalytic Application to CO2 Cycloaddition with Propylene Epoxide |
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| YIN Shuang-feng,DAI Wei-li,LI Wen-sheng,ZHOU Xiao-ping,SHIMADA Shigeru. Synthesis of Novel Organobismuth Complexes Bearing a Sulfur-bridged Biphenolate Ligand and Their Catalytic Application to CO2 Cycloaddition with Propylene Epoxide[J]. Journal of Molecular Catalysis (China), 2007, 21(3): 264-267 |
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| Authors: | YIN Shuang-feng DAI Wei-li LI Wen-sheng ZHOU Xiao-ping SHIMADA Shigeru |
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| Affiliation: | 1. College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, Hunan, China; National Institute of Advanced Industrial Science and Technology ( AIST |
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| Abstract: | Novel organobismuth complexes bearing a sulfur-bridged biphenolate ligand were synthesized and characterized.They show high catalytic activity and selectivity for the solvent-free synthesis of propylene carbonate from CO2 cycloaddition with propylene oxide in the presence of iodide nucleophilic reagents. |
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| Keywords: | Organobismuth complex Carbon dioxide Propylene oxide Propylene carbonate Cycloaddition reaction |
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