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Palladium-catalyzed esterification of aryl halides using aryl formates without the use of external carbon monoxide
Authors:Tetsuaki Fujihara  Tomoya Hosoki  Yuko Katafuchi  Tomohiro Iwai  Jun Terao  Yasushi Tsuji
Affiliation:Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Kyoto 615-8510, Japan.
Abstract:Aryl formates are efficient carbon monoxide sources in palladium-catalyzed esterification of aryl halides. The carbonylation readily proceeds at ambient pressure without the use of external carbon monoxide to afford the corresponding esters in high yields.
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