| 有机-无机杂化一维纳米材料的合成及其二次转化 |
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| 引用本文： | 王思浓,高庆生,陈平,毛建江,武庆斌,张亚红,唐颐. 有机-无机杂化一维纳米材料的合成及其二次转化[J]. 中国科学:化学, 2012, 0(11): 1598-1615 |
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| 作者姓名： | 王思浓 高庆生 陈平 毛建江 武庆斌 张亚红 唐颐 |
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| 作者单位： | [1]上海市分子催化与功能材料重点实验室；复旦大学化学系,上海200433 [2]暨南大学化学系,广州510632 |
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| 摘 要： | 近十年来，随着纳米科技的发展，有机．无机杂化一维纳米材料的设计合成与应用成为了自然科学领域的研究热点．本文综述了由有机小分子与无机组分杂化而成的一维纳米材料的合成方法，包括水热／溶剂热法、共沉淀法、非水相溶胶凝胶法、模板法、后嵌入法等．并对有机一无机杂化一维纳米材料的二次转化，如通过二次转化获得功能性一维氧化物、碳氮化物、硫属化合物及高分子杂化纳米材料，进行了讨论与展望．
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| 关 键 词： | 有机-无机杂化 一维纳米材料 合成方法 二次转化 |
Synthesis and transformation of one-dimensional organic-inorganic hybrid nanomaterials |
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| WANG SiNong,GAO QingSheng,CHEN Ping,MAO JianJiang,WU QingBin,ZHANG YaHong,TANG Yi. Synthesis and transformation of one-dimensional organic-inorganic hybrid nanomaterials[J]. Scientia Sinica Chimica, 2012, 0(11): 1598-1615 |
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| Authors: | WANG SiNong GAO QingSheng CHEN Ping MAO JianJiang WU QingBin ZHANG YaHong TANG Yi |
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| Affiliation: | 1 Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials; Department of Chemistry, Fudan University, Shanghai 200433, China 2 Department of Chemistry, Jinan University, Guangzhou 510632, China |
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| Abstract: | In the last decade, the synthesis and application of one-dimensional （1D） organic-inorganic hybrid nanomaterials have attracted increasing attention in the fields of physics, chemistry, material science, biology, etc, with the development of nanotechnology. In this review, we summarized the synthetic methods of small organic molecule- containing 1D organic-inorganic hybrid nanomaterials, including hydrothermal/solvothermal, co-precipitation, nonaqueous sol-gel, template and intercalation methods. The strategies for the preparation of functional 1D materials via the second transformation of the 1D organic-inorganic hybrid precursors are also discussed and prospected. |
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| Keywords: | organic-inorganic hybrid materials one-dimensional nanomaterials synthesis second transformation |
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