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尖晶石LiMn_2O_4高温电化学容量衰减及改进
引用本文:陈召勇,刘兴泉,高利珍,于作龙.尖晶石LiMn_2O_4高温电化学容量衰减及改进[J].无机化学学报,2001,17(3).
作者姓名:陈召勇  刘兴泉  高利珍  于作龙
作者单位:中国科学院成都有机化学研究所功能材料开发中心,
基金项目:国家科技部重点资助项目(No.98-D102)。
摘    要:综述了高温下尖晶石LiMn2O4容量衰减的原因、机理研究和改进它的高温性能的方法以及目前的进展,且指出了可能的提高它的高温性能的途径。

关 键 词:尖晶石LiMn_2O_4  高温性能  阴极材料

Electrochemical Capacity Fading in High Temperature of Spinel LiMn_2O_4 and its Improvement
Chen Zhao-Yong,LIU Xin-quan,GAO Li-Zhen,YU Zuo-Long.Electrochemical Capacity Fading in High Temperature of Spinel LiMn_2O_4 and its Improvement[J].Chinese Journal of Inorganic Chemistry,2001,17(3).
Authors:Chen Zhao-Yong  LIU Xin-quan  GAO Li-Zhen  YU Zuo-Long
Abstract:The reason for capacity fading and mechanism of spinel LiMn2O4 in high temperature was reviewed, and the capacity fading was mainly caused by the dissolution of manganese, oxidation of electrolyte, and the polarization of electrode. At the same time the solutions and progresses for improving the property of spinel LiMn2O4 in high temperature were also included in this paper, and adding other ions, decreasing the surface of cathode materials, and coating the positive materials were efficiently used to improve its high temperature performance. Furthermore, some methods which can possibly suppresses the capacity fade were suggested.
Keywords:spinel LiMn_2O_4  high temperature property  cathode materials  
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