Some time after its formation an exotic atom may be considered a hydrogen-like system consisting of a nucleus and an exotic particle in a bound state. In this situation it is an ideal tool to study cascade properties, while for the innermost orbits it can be used to probe the interaction with the nucleus. From an extended series of experiments using high resolution X-ray spectroscopy for both aspects typical examples are reported and preliminary results are given: 1. To determine the complex scattering length in H the hyperfine transitions have been measured. 2. To determine the pion mass the 5 4 transitions in N have been studied. In all cases a major contribution to the uncertainty originates from the calibration. Therefore a new method is proposed that will establish a universal set of high precision calibration lines for pionic, muonic and electronic systems. This revised version was published online in July 2006 with corrections to the Cover Date.