Synthesis of 8,12-Dibromocorrole and Its Transformation to Antiaromatic 8,10-Fused Iminoisocorrole with a Polarized Resonance Contribution

8,12-Dibromo-5,15-bis(pentafluorophenyl)corrole and its Ag(III) complex were prepared via intramolecular oxidative coupling of a 8,12-dibromobilane precursor. The Ag(III) complex was allowed for further transformation via Suzuki coupling reaction. Thus, 2-aminophenyl group was coupled at one of the β-positions, and subsequent demetalation followed by oxidation with MnO₂ afforded 8,10-fused iminoisocorrole in good yields. The iminoisocorrole exhibited weak antiaromaticity due to the C(+)−N(−) polarized resonance contribution as evidenced by ¹H NMR spectrum, UV/vis absorption spectra, cyclic voltammetry, and theoretical calculations.