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Supported Palladium-Catalyzed Carbonylative Synthesis of Diaryl Ketones from Aryl Bromides and Arylboronic Acids |
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| Authors: | Dr Tiefeng Xu Qi Wang Zeyi Yang Dr Lili Yi Jian-Shu Wang Prof Dr Wangyang Lu Dr Jun Ying Prof Dr Xiao-Feng Wu |
| Institution: | 1. National Engineering Lab for Textile Fiber Materials & Processing Technology, Zhejiang Sci-Tech University, Hangzhou, 310018 P. R. China
These authors contributed equally to this work.;2. Department of Chemistry, Key Laboratory of Surface & Interface Science of Polymer Materials of Zhejiang Province, Zhejiang Sci-Tech University, Hangzhou, 310018 P. R. China These authors contributed equally to this work.;3. National Engineering Lab for Textile Fiber Materials & Processing Technology, Zhejiang Sci-Tech University, Hangzhou, 310018 P. R. China;4. Department of Chemistry, Key Laboratory of Surface & Interface Science of Polymer Materials of Zhejiang Province, Zhejiang Sci-Tech University, Hangzhou, 310018 P. R. China;5. Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023 Liaoning, P. R. China |
| Abstract: | A palladium supported on graphitic carbon nitride (Pd/g-C3N4) catalyzed carbonylative reaction of aryl bromides and arylboronic acids by has been developed for the construction of diaryl ketones. Using benzene-1,3,5-triyl triformate (TFBen) as the CO source, the reaction proceeded well to give various diaryl ketones in moderate to good yields. |
| Keywords: | Palladium catalysis Carbonylation Suzuki coupling Ketone Heterogeneous catalyst |