Solubility products,thermodynamic functions and stability constants for the praseodymium and ytterbium fluoride — Water systems

The solubility products and thermodynamic functions for the praseodymium and ytterbium fluoride-water systems have been measured using different analytical techniques for comparison among the measured values as well as with values reported in literature. Although there is not much difference among our values obtained by potentiometric, conductometric and radiometric methods, the values for PrF₃ disagree with at least two of the reported values. The effects of precipitant, aging of the precipitate and pH of the saturated solutions on the solubility product were studied and found to be significant. The standard enthalpy and free energy changes for the dissolution of both fluorides were found to be positive although the enthalpy for YbF₃ is about twice as high as that for PrF₃. The standard entropy change for PrF₃ is negative, but that for YbF₃ is positive. The overall stability constants for the mono- and difluoride complexes of both Pr and Yb have also been measured potentiometrically using a simplified approach.