CoAu2(CN)4(NITpPy)2(H2O)2]n: a new 2-D interdigitating complex containing dicyanoaurate(I) anion, a radical, and cobalt(II) ion incorporating gold...gold and hydrogen bonding interactions |
| |
Authors: | Zhou Hui-Bo Wang Shu-Ping Dong Wen Liu Zhan-Quan Wang Qing-Lun Liao Dai-Zheng Jiang Zong-Hui Yan Shi-Ping Cheng Peng |
| |
Institution: | Department of Chemistry, Nankai University, Tianjin 300071, P. R. China. |
| |
Abstract: | A novel complex, CoAu2(CN)4(NITpPy)2(H2O)2]]n, 1, containing the cobalt(II) ion, dicyanoaurate(I) anion, and nitronyl nitroxide radical building blocks, has been prepared and structurally characterized by single-crystal X-ray analysis. The structure of complex 1 illustrates that aurophilicity and hydrogen bonding interactions increase dimensionality, generating a 2-D interdigitating system. The spectroscopic and magnetic properties have been investigated. |
| |
Keywords: | |
本文献已被 PubMed 等数据库收录! |
|