Polystyrene-supported TiCl4 as a novel,efficient and reusable polymeric Lewis acid catalyst for the chemoselective synthesis and deprotection of 1,1-diacetates under eco-friendly conditions |
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Authors: | Ali Rahmatpour Sara Mohammadian |
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Institution: | Polymer Science and Technology Division, Research Institute of Petroleum Industry (RIPI), 14665-1137 Tehran, Iran |
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Abstract: | Copolymer beads of styrene and divinylbenzene (5–7%) were synthesized and combined with titanium tetrachloride in CS2 to form a stable complex. The PS/TiCl4 complex was used as a mild and efficient polymer-supported Lewis acid catalyst for the preparation of 1,1-diacetates from various types of aldehydes under heterogeneous conditions at room temperature. Deprotection of the resulting 1,1-diacetates has also been achieved using the same catalyst in methanol. This new protocol has the advantages of easy availability, stability, reusability of the eco-friendly catalyst, high to excellent yields, chemoselectivity, simple experimental and work-up procedure. Moreover, this polymeric catalyst could be recovered easily and reused several times without significant loss in activity. |
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Keywords: | Polymer-supported catalyst 1 1-diacetate Chemoselectivity Heterogeneous Lewis acid catalyst Aldehydes Protection |
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