| 特征参量法 2: 可逆反应 |
| |
| 引用本文： | 张元勤,曾宪诚,胡启山,田安民.特征参量法 2: 可逆反应[J].化学学报,1998,56(2):129-134. |
| |
| 作者姓名： | 张元勤 曾宪诚 胡启山 田安民 |
| |
| 作者单位： | 四川大学化学系;达县师范专科学校化学系 |
| |
| 基金项目： | 国家自然科学基金，29502008， |
| |
| 摘 要： | 根据几类可逆反应通用的微分动力学方程和热动力学变换方程,本文建立了可逆反应的特征参量研究法。应用该法在两个温度下研究了硝基乙烷分别与氨和Tris反应的热动力学, 实验结果验证了可逆反应特征参量法的正确性。
|
| 关 键 词： | 硝基化合物 反应动力学 氨 乙烷P 可逆反应 特征参量法 |
| 修稿时间： | 1996年7月30日 |
Characteristic parameter method II. Thermokinetic research method of reversible reactions |
| |
| ZHANG Yuan-Qin,ZENG Xian-cheng,HU Qi-Shan,TIAN An-min.Characteristic parameter method II. Thermokinetic research method of reversible reactions[J].Acta Chimica Sinica,1998,56(2):129-134. |
| |
| Authors: | ZHANG Yuan-Qin ZENG Xian-cheng HU Qi-Shan TIAN An-min |
| |
| Abstract: | According to the general differential kinetic equation of several types of reversible reactions and the thermokinetic transformation equation, the characteristics parameter method for reversible reactions, with which the rate constants of forward and backward reactions and equilibrium constant can be obtained simultaneously from a single thermogram, has been proposed in this paper. The thermokinetics of the reactions of nitroethane with ammonia at 15℃ and 25℃ and with trihydroxymethyl aminomethane at 15℃ and 30℃ have been studied with this method respectively. The validity of this method has been proved by the experimental results. |
| |
| Keywords: | thermokinetics thermokinetic research method characterstic parameter method reversible reation |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
| 点击此处可从《化学学报》浏览原始摘要信息 |
| 点击此处可从《化学学报》下载免费的PDF全文 |
