The mass spectra of some diterpene lactones |
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Authors: | R. Hodges R. C. Cambie K. N. Joblin |
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Abstract: | The molecular ions of some diterpenoid trans-γ-and δ-lactones have been shown to lose the elements of carbon dioxide. The corresponding cis-lactones do not undergo fission in this manner. A mechanism for this stereospecific fragmentation is proposed. |
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