Über die Darstellung von Verbindungen des Typs Cl3VNR

The reaction of VOCl₃ with sily-substituted amines results in the substitution of oxygen in VOCl₃ and in compounds of type Cl₃V = NR. In this way, we succeeded in isolating the pure compound Cl₃V = NCH₃ (I). The existence of compound (Cl₃VNC₆H₅)_x (II) was proved by direct synthesis from Cl₃VO and ((CH₃)₃Si)₂NC₆H₅, and by the decomposition of the new addition compounds Cl₃VO · 2 OCNC₆H₅ (III) and Cl₃VO · 2 OSNC₆H₅ (IV).