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聚氨酯/分子筛复合材料的制备及性能
引用本文:刘运学,王杨松,范兆荣,谷亚新,翟玉春. 聚氨酯/分子筛复合材料的制备及性能[J]. 分子科学学报, 2008, 24(4)
作者姓名:刘运学  王杨松  范兆荣  谷亚新  翟玉春
作者单位:1. 东北大学材料与冶金学院,辽宁,沈阳,110004;沈阳建筑大学材料学院,辽宁,沈阳,110168
2. 沈阳建筑大学材料学院,辽宁,沈阳,110168
3. 东北大学材料与冶金学院,辽宁,沈阳,110004
摘    要:以聚对苯二甲酸乙二醇酯(PEA)、甲苯二异氰酸酯(TDI-80)、扩链剂(MOCA)、分子筛为原料,采用预聚体法制备了聚氨酯/分子筛复合材料.考察了分子筛的种类及加入量对聚氨酯/分子筛复合材料的耐溶剂性能、力学性能及热分解温度的影响.结果表明:在相同加入量的前提下,采用4A和13X分子筛制备的复合材料,前者的耐溶剂性能及力学性能要优于后者,当加入量为5%时,性能达到最佳.两者的加入均能提高复合材料的热分解温度,但影响相差不大.

关 键 词:聚氨酯  分子筛  复合材料

Investigation on the synthesis and properties of PU/zeolite composites
LIU Yun-xue,WANG Yang-song,FAN Zhao-rong,GU Ya-xin,ZHAI Yu-chun. Investigation on the synthesis and properties of PU/zeolite composites[J]. Journal of Molecular Science, 2008, 24(4)
Authors:LIU Yun-xue  WANG Yang-song  FAN Zhao-rong  GU Ya-xin  ZHAI Yu-chun
Abstract:The polyurethane/zeolite composites was prepared by pre-polymerization method,with the polyethylene glycol adipate(PEA),toluene ditscoyanate(TDI-80),extender(MOCA)and zeolite.It was investigated that the effect of the kinds of zeolite on the mechanical properties and solvent resistance of PU/zeolite composites.The results showed that the mechanical properties and solvent resistance of PU/4A zeolite composites was better than PU/13X zeolite composites under the same addition of zeolite.And the properties of PU/zeolite composites was best when the loading of zeolite was 5%.Compared with pure PU,the thermal stability of PU/zeolite composites was improved.
Keywords:polyurethane  zeolite  composites
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