| Synthesis,Structure, and DNA Binding of a Platinum(Ⅱ) Complex Based on the 3,4,5-Trimethoxy-phenyl-1H-imidazo[4,5-f][1,10]phenanthroline |
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| 引用本文： | 黎晓,罗旭健,杨燕,马利,王书龙,罗志辉,刘荣军,梁伟江.Synthesis,Structure, and DNA Binding of a Platinum(Ⅱ) Complex Based on the 3,4,5-Trimethoxy-phenyl-1H-imidazo[4,5-f][1,10]phenanthroline[J].结构化学,2018(5). |
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| 作者姓名： | 黎晓 罗旭健 杨燕 马利 王书龙 罗志辉 刘荣军 梁伟江 |
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| 摘 要： | A new platinum(Ⅱ) complex of Pt(chda)(3,4,5-triopip)]Cl·2H_2O(1) based on 3,4,5-trimethoxy-phenyl-1 H-imidazo4,5-f]1,10]phenanthroline(3,4,5-triopip) has been synthesized by hydrothermal methods and its consequences are characterized by elemental analysis, IR, single-crystal X-ray diffraction, UV-Vis absorption and fluorescent spectrum. The UV-Vis absorption studies reveal that the molecule undergoes considerable interaction with the nucleic acid. In this mononuclear structure, the platinum adopts a four-coordinated square planar geometry, which may favor the intercalation between the neighboring bases of the G-quadruplex(G4) DNA.
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