| Syntheses,Structures, and Properties of Two Cobalt(Ⅱ) Coordination Complexes Based on(Fluorene-9,9-diyl) dipropanoic Acid and 1,3-Bis(imidazol-1-yl)butane Ligands |
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| 引用本文： | 田雨滨,王梦,张文,宋楠楠,宋新建,胡卫兵,冯驸.Syntheses,Structures, and Properties of Two Cobalt(Ⅱ) Coordination Complexes Based on(Fluorene-9,9-diyl) dipropanoic Acid and 1,3-Bis(imidazol-1-yl)butane Ligands[J].结构化学,2018(7). |
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| 作者姓名： | 田雨滨 王梦 张文 宋楠楠 宋新建 胡卫兵 冯驸 |
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| 摘 要： | Two new cobalt(II) coordination complexes, namely Co(HL)_2(biim)(H_2O)_2]_n·n H_2O(1) and Co(Et L)_2(biim)]_n·3 n(H_2O)·2 n(Et HL)(2)(H_2L =(fluorene-9,9-diyl)dipropanoic acid, biim = 1,3-bis(imidazol-1-yl)butane), have been synthesized using the same starting reactants but different solvent medium. The two complexes exhibit distinctly different structures. Compound 1 exhibits a one-dimensional linear chain structure. However, complex 2 reveals a one-dimensional zigzag chain structure. Thermogravimetric analyses(TGA) and luminescent properties of these two complexes have been discussed.
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