Facile synthesis and characterization of acid-base bifunctionalized mesoporous silica |
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Authors: | Ying Chen Haitao Zhang |
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Affiliation: | Key Laboratory for Green Chemical Technology of State Education Ministry, School of Chemical Engineering & Technology, Tianjin University, No. 92 Weijin Road, Nankai District, Tianjin 300072, PR China |
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Abstract: | A simple acid-base bifunctionalized approach has been developed through grinding the precursors, magnesium and aluminium nitrates, with the as-prepared SBA-15, and then the generation of acid-base active sites and removal of host template were combined into a single step in the subsequent calcination procedure. A series of acid-base bifunctional mesoporous materials MgO-Al2O3-SBA-15 (MA-SBA-15) have been successfully synthesized by means of this approach. X-ray diffraction (XRD), high-resolution transmission electron microscopes (HRTEMs), N2 adsorption, FT-IR spectra, 27Al and 29Si magic-angle-spinning (MAS) NMR, NH3- and CO2-temperature programmed desorption (TPD), pyridine adsorption were employed to characterize the resultant mesoporous materials. The results indicate that the guests can be well dispersed in the channel of SBA-15, and the resultant materials exhibit excellent acid-basic properties with well mesoporous backbone, which make it possessing high activity for the synthesis of ethyl methyl carbonate, an important asymmetric carbonate ester compound. |
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Keywords: | Mesoporous materials Acid-base properties MgO-Al2O3-SBA-15 Surface functionalization |
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