Rational design of molecular sheets composed of interconnecting eight- and twenty-four-membered rings: use of lithiated aggregates to control network assembly |
| |
Authors: | Henderson Kenneth W Kennedy Alan R Macdonald Lynn MacDougall Dugald J |
| |
Affiliation: | Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, IN 46556-5670, USA. khenders@nd.edu |
| |
Abstract: | The lithiated (organo)sulfonylacetonitrile complex [MeSO(2)CHCNLi.THF] (3) has been prepared and structurally characterized in order to demonstrate that well-known molecular aggregates of s-block metals may be used as building blocks in the controlled assembly of complex supramolecular architectures. The solid state structure of 3 can be described as a novel basket-weaved, 2-D network, composed of (SO(2)Li)(2) "dimeric" rings joined via "interdimer" donation of nitrile units. |
| |
Keywords: | |
本文献已被 PubMed 等数据库收录! |
|