Synthesis and reactivity of a uranyl-imidazolyl complex |
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| Authors: | Schettini Michael F Wu Guang Hayton Trevor W |
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| Institution: | Department of Chemistry and Biochemistry, University of California Santa Barbara, Santa Barbara, CA 93106, USA. |
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| Abstract: | Treatment of UO(2)(Ar(2)nacnac)Cl](2) with 4 equiv. of Li(C(4)H(5)N(2)) results in the formation of a rare uranyl organometallic complex Li(MeIm)]UO(μ-O)(Ar(2)nacnac)(μ-C,N-C(4)H(5)N(2))(2)] (2), in moderate yield. Reaction of 2 with 1 equiv. of MCl(2) (M = Fe, Co) yields the bimetallic complexes MCl(MeIm)]UO(2)(Ar(2)nacnac)(μ-N,C-C(4)H(5)N(2))(2)] (M = Fe, 3; M = Co, 4). |
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