Measurements of heavy-atom isotope effects using 1H NMR spectroscopy |
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| Authors: | Pabis Anna Kamiński Rafał Ciepielowski Grzegorz Jankowski Stefan Paneth Piotr |
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| Affiliation: | Institute of Applied Radiation Chemistry, Faculty of Chemistry, Technical University of Lodz, Zeromskiego 116, 90-924 Lodz, Poland. |
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| Abstract: | A novel method for measuring heavy-atom KIEs for magnetically active isotopes using (1)H NMR is presented. It takes advantage of the resonance split of the protons coupled with the heavy atom in the (1)H spectrum. The method is validated by the example of the (13)C-KIE on the hydroamination of styrene with aniline, catalyzed by phosphine-ligated palladium triflates. |
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